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This is a colorful and estatically pleasing experiment. Colors ranging
from...
are shown by Copper(II) compounds. |
This contrasts with the pale yellows and whites of
Copper(I) compounds.... |
... This synthesis starts with copper metal which is converted to the nitrate by reaction with concentrated Nitric Acid. This equation is not
balanced |
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... This copper(II)
nitrate needs to be converted to copper(II) chloride which is then reduced to the desired copper(I) chloride. Cu(NO3)2 + Na2CO3 ------> CuCO3 + 2 NaNO3 CuCO3 + 2 HCl -----> CuCl2 + CO2 + H2O The green Copper(II) Chloride is converted to the dark brown tetrachlorocuprate(II) ion with excess Hydrochloric Acid and reduced with copper metal to a pale yellow copper(I) chloro complex. CuCl4-2 + Cu -----> 2 CuCl3-2 The color of the solution shows the degree of reaction |
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The above transitions happen in the course of 15 to 30 minutes. |
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© RWK 1/98